Pioneer P-31 (also known as Atlas-Able 5B or Pioneer Z) was intended to be a lunar orbiter probe, but the mission failed shortly after launch. The objectives were to place a highly instrumented probe in lunar orbit, to investigate the environment between the Earth and Moon, and to develop technology for controlling and maneuvering spacecraft from Earth. It was equipped to take images of the lunar surface with a television-like system, estimate the Moon's mass and topography of the poles, record the distribution and velocity of micrometeorites, and study radiation, magnetic fields, and low frequency electromagnetic waves in space. A mid-course propulsion system and injection rocket would have been the first U.S. self-contained propulsion system capable of operation many months after launch at great distances from Earth and the first U.S. tests of maneuvering a satellite in space.
The spacecraft was launched on an Air Force-Convair Atlas D intercontinental ballistic missile coupled to Thor-Able upper stages including an Able solid propellant third stage. The vehicle exploded 68 seconds after launch at an altitude of 12 km due to a malfunction in the first stage. The payload fell into the Atlantic Ocean 12 to 20 km from Cape Canaveral in about 20 meter deep water.
Pioneer P-31 was virtually identical to the earlier Pioneer P-30 satellite which failed, a 1 meter diameter sphere with a propulsion system mounted on the bottom giving a total length of 1.4 meters. The mass of the structure and aluminum alloy shell was about 30 kg and the propulsion units roughly 90 kg. Four solar panels, each 60 x 60 cm and containing 2200 solar cells in 22 100-cell nodules, extended from the sides of the spherical shell in a "paddle-wheel" configuration with a total span of about 2.7 meters. The solar panels charged nickel-cadmium batteries. Inside the shell, a large spherical hydrazine tank made up most of the volume, topped by two smaller spherical nitrogen tanks and a 90 N injection rocket to slow the spacecraft down to go into lunar orbit, which was designed to be capable of firing twice during the mission. Attached to the bottom of the sphere was a 90 N vernier rocket for mid-course propulsion and lunar orbit maneuvers which could be fired four times.
Around the upper hemisphere of the hydrazine tank was a ring-shaped instrument platform which held the batteries in two packs, two 1.5 W UHF transmitters and diplexers, logic modules for scientific instruments, two command receivers, decoders, a buffer/amplifier, three converters, a telebit, a command box, and most of the scientific instruments. Two dipole UHF antennas protruded from the top of the sphere on either side of the injection rocket nozzle. Two dipole UHF antennas and a long VLF antenna protruded from the bottom of the sphere. The transmitters operated on a frequency of 378 megahertz.
Thermal control was planned to be achieved by fifty small "propeller blade" devices on the surface of the sphere. The blades themselves were made of reflective material and consist of four vanes which were flush against the surface, covering a black heat-absorbing pattern painted on the sphere. A thermally sensitive coil was attached to the blades in such a way that low temperatures within the satellite would cause the coil to contract and rotate the blades and expose the heat absorbing surface, and high temperatures would cause the blades to cover the black patterns. Square heat-sink units were also mounted on the surface of the sphere to help dissipate heat from the interior.
The scientific instruments consisted of an ion chamber and Geiger-Mueller tube to measure total radiation flux, a proportional radiation counter telescope to measure high energy radiation, a scintillation counter to monitor low-energy radiation, a scintillation spectrometer to study the Earth's (and possible lunar) radiation belts, a VLF receiver for natural radio waves, a transponder to study electron density, and part of the flux-gate and search coil magnetometers mounted on the instrument platform. A plasma probe was mounted on the sphere to measure energy and momentum distribution of protons above a few kilovolts to study the radiation effect of solar flares. The micrometeorite detector and sun scanner were mounted on the sphere as well. The only difference between Pioneer P-31 and the earlier Pioneer P-30 was the addition of a solid state detector sensitive to low energy protons on the satellite and an STL-designed rubidium frequency standard experiment placed on a pod attached to the booster. The total mass of the science package including electronics and power supply was roughly 60 kg. Total cost of the mission was estimated at 9 - 10 million dollars.